Cotton dyeing with sulfur black dye

Md Mahedi Hasan

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Defectively dyed apparel is made into one or more batches to dye with sulfur black dyes.

Process of Cotton dyeing:

  • L: R = 1: 10 (for 150 kg)
  • 60 kg salt @ 40% of liquor
  • Raise temp. to 60º C by steam supply.
  • After 15 min add sulfur black @ 12% + Sodium Hydrosulfide @ 14% of liquor
  • Raise temp. to 80º C and continue processing for 120 mins.
  • Raise temp. to 90º C add Sodium Carbonate @ 5%. Continue processing for 60 mins.
  • Reduce dyeing temp. 70º C and drop the dye liquor
Cotton Garments Dyeing Process
Image of Cotton Dyeing Process
  • To remember unfixed dye, a hot wash at 50º C with 0.5% detergent for 15 minutes with 1500 liter water. Continue washing for 5 mins without temperature 
  • Sulfur black-dyed garments if stored, may form sulfuric acid which will reduce garment strength. To avoid this, 3% unidol SF paste may be used.
  • Dyeing with sulfur dye is very dirty work for m/c, the floor, operators & environment should be cleaned well for further processing. 

Cotton sweater dyeing with pigment:

1. Pretreatment (Bleaching, scouring)

L :R = 1 : 25Detergent (Filose) @ 0.5 g/LSoda ash @ 2 g/LCaustic Soda @ 3g/LH2O2 @ 3ml/LTemp = 900C; Time= 40 min

 2. Singeing:

Cellulose (Denimex 992 L)) Enzyme @ 1 g/L

Acetic acid = PH 4.5

Temp. = 550C

Time= 30 min

3. Pigment dyeing:

Cationic agent (Prifix K) 1g/L

Soda ash = PH 8.5

Pigment Red H3BD @ 0.5% anionic pigment forms a bond with cationic cotton

Binder @ 1g/L forms a preliminary net structure with pigment and fabric

4. Washing:

Softener 0.5 g/L

Acetic acid = 5.5 PH

  • During drying, the final fixation of the binder takes place.

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